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41.
New Macrolides and Some Sesquiterpenoid Derivatives Occurring in Galbanum Absolute Analytical investigations of a Galbanum absolute have revealed for the first time the presence of four macrolides 1 – 4 derived from the corresponding hydroxylated C13–C16 fatty acids by lactonization of a secondary alcoholic group with the carboxylic group. The musky odor strengthens with increasing number of members in the macrocycle, whereas the woody note is predominant in the smaller rings. Isolation, identification and synthesis of the new naturally occurring substances are described. Shyobunol ( 24 ) epishyobunol ( 25 ) as well as their acetates 26 and 27 were identified - together with 10-epijunenyl acetate ( 28 ) - in the same substrate, thus indicating 25 and 26 to be natural products. The corresponding known and already naturally occurring ketones 23 and 24 are trace components in the investigated material derived from the so-called Galbanum oleo-gum-resin. 相似文献
42.
Martina Nveke Peter G. Jones Armand Blaschette Dietmar Schomburg Heiko K. Cammenga Matthias Epple 《无机化学与普通化学杂志》1993,619(6):1027-1036
Polysulfonyl Amines. XLI. A Silver(I) Hydrate with an Unusual Composition: Characterization of Tetrakis(dimesylamido)aquatetrasilver(I) [Ag4(N)SO2CH3)2}4(H2O)] by X-Ray Diffraction and Thermal Analysis The title compound is obtained by crystallizing AgN(SO2CH3)2 from water at room temperature. Crystallographic data (at ?95°C): Triclinic space group P1 , a = 864.6(4), b = 1 211.2(5), c = 1 399.1(5) pm, α = 90.97(3), β = 90.90(3), γ = 98.25(4)°, V = 1.4496 nm3, Z = 2, Dx = 2.608 Mg m?3. The four independent silver atoms and the water molecule form zigzag chains Ag(1)-Ag(2)-(μ-H2O)-Ag(3) …? Ag(4) …? Ag(1′) with distances Ag(1)-Ag(2) 309.7, Ag(2)-O(w) 241.8, O(w)-Ag(3) 241.4, Ag(3) …? Ag(4) 342.9, Ag(4) …? Ag(1′) 361.4 pm. The catenated silver atoms are further connected by the dimesylamide anions acting as tridentate bridging (α-O, N, ω-O)-ligands. The resulting strands are interconnected into layers through one O(S)-Ag′ contact (247 pm) and one hydrogen bond O(w)-H(l) …? O′(S) per repeating unit. Between the layers, a weak O(S) …? Ag″ interaction (271 ptn) and a hydrogen bond O(w)-H(2) …? O(S) per repeating unit are observed. The silver atoms Ag(l) to Ag(4) display the coordination numbers 5 [NO,Ag(2), distorted trigonal bipyramid], 5[NO2,O(w)Ag(I), distorted trigonal bipyramid], 5[O4,O(w), trigonal bipyramid], and 2 + 1 (N2, li-near; plus a secondary Ag …? 0 contact). The dehydration of the title compound and a solid-solid phase transformation in anhydrous AgN(SO2CH3)2, were quantitatively investigated by thermoconductometry and time- and temperature-resolved X-ray diffractometry (TXRD). 相似文献
43.
Dietmar Stuewer 《Fresenius' Journal of Analytical Chemistry》1990,337(7):737-742
Summary Among recent MS techniques for elemental analysis, Glow Discharge Mass Spectrometry (GDMS) covers the field of direct analysis of conducting and semiconducting solids. In GDMS, a glow discharge in a working gas — usually Ar — at reduced pressure serves to atomize a solid sample by cathodic sputtering and to ionize the vapourized atoms. Ions are separated according to mass by a quadrupole filter (with low mass resolution) or a double focusing device (with high mass resolution). Use of a working gas implies the appearance of spectral interferences by molecular ions. Analysis may be impeded by these interferences, even in the case of high mass resolution. GDMS shows convincing analytical performance. Detection limits in the low ng/g region and even below can easily be realized. Precision is normally in the low percentage region, and a dynamic region of about nine orders of magnitude may be covered. Matrix effects are of no significant influence, and elemental sensitivities are within one order of magnitude. Semiquantitative analysis without standards is possible with limited accuracy, which is of considerable practical interest in the sub-microtrace region. Application experiences have mainly been gathered in analysis of very pure materials and semiconductors. GDMS has also been applied successfully for analytical characterization of technical surface layers. 相似文献
44.
The design and synthesis of molecules containing both a substrate-binding cavity and a nearby catalytically active metal center is a useful approach to the development of synthetic systems that function according to the principles of enzymes. To this end the receptor molecule 2a, derived from diphenylglycoluril, was functionalized with triaryl phosphite ligands to give the receptor ligand 2d. Exchange reactions of 2d with (diketonate)Rh(CO)(2), (diketone = acetylacetone, dibenzoylmethane, or dipivaloylmethane) led to the formation of the metallohosts 3a-c, respectively. The properties and conformational behavior of these metal complexes were studied by NMR techniques. Reaction of compounds 3 with H(2) in the presence of a small excess of additional triphenyl phosphite yields the rhodium(I) hydride complex 5. The metallohosts are capable of binding dihydroxybenzene guests in their cavities by hydrogen bonding and pi-pi stacking interactions. On binding a substrate the conformational behavior of hosts 3a-c was affected considerably. 相似文献
45.
Sautter A Kaletas BK Schmid DG Dobrawa R Zimine M Jung G van Stokkum IH De Cola L Williams RM Würthner F 《Journal of the American Chemical Society》2005,127(18):6719-6729
A molecular square with dimensions of about 4 nm, incorporating sixteen pyrene chromophores attached to four ditopic bay-functionalized perylene bisimide chromophores, has been synthesized by coordination to four Pt(II) phosphine corner units and fully characterized via NMR spectroscopy and ESI-FTICR mass spectrometry. Steady-state and time-resolved emission as well as femtosecond transient absorption studies reveal the presence of a highly efficient (>90%) and fast photoinduced energy transfer (k(en) approximately equal to 5.0 x 10(9) s(-1)) from the pyrene to the perylene bisimide chromophores and a very fast and efficient electron transfer (>94%, k(et) approximately equal to 5 x 10(11) up to 43 x 10(11) s(-1)). Spectrotemporal parametrization indicates upper excited-state electron-transfer processes, various energy and electron-transfer pathways, and chromophoric heterogeneity. Temperature-dependent time-resolved emission spectroscopy has shown that the acceptor emission lifetime increases with decreasing temperature from which an electron-transfer barrier is obtained. The extremely fast electron-transfer processes (substantially faster and more efficient than in the free ligand) that are normally only observed in solid materials, together with the closely packed structure of 20 chromophoric units, indicate that we can consider the molecular square as a monodisperse nanoaggregate: a molecularly defined ensemble of chromophores that partly behaves like a solid material. 相似文献
46.
47.
48.
The analytical performance of a glow discharge quadrupole mass spectrometer is demonstrated using sintered tungsten as an example. The inherent problem of molecular interferences in glow discharge mass Spectrometry has been considerably reduced using neon as a complementing discharge gas. Particular attention has been paid to time dependences. Analytical figures of merit are presented. 相似文献
49.
The occurrence of a series of new constituents which can be considered as Diels-Alder adducts of methyl vinyl ketone and ocimene (→1–4), myrcene (→ 9 , 10 ) or β-far-nesene ( → 11 , 12 ), respectively, was reported. Furthermore, the structures of four isomeric cyclohexene derivatives could be established as adducts 21–24 of (E, Z)- and (E, E)-1,3,5-undecatrience and methyl vinyl ketone. Another series of constituents having the norbornane skeleton represents adducts 25–32 , and 33–40 of methyl cyclopentadiene and 1-octen-3-one or methyl vinyl ketone, respectively. In accordance with Alder's endo-rule the endo-isomers are preponderant in the natural as well as in the synthetic mixtures. Most of these constituents could also be identified in a lavender absolute as well as in a freshly prepared hexane extract of lavender flowers (Lavandula officinalis CHAIX ). 相似文献
50.
Sabine Rentsch Gudrun Hermann Mark Bischoff Dietmar Strehlow Manfred Rentsch 《Photochemistry and photobiology》1997,66(5):585-590
Abstract— The excited state behavior of the red light-absorbing form of phytochrome (Pr) was studied on the femtosecond time scale. After excitation of Pr with 75 fs laser pulses at 616 nm the kinetics of the transient absorption changes was recorded at selected wavelengths probing mainly the bleaching of the Pr ground-state absorption and the stimulated emission. The kinetic data obtained indicate the population of an excited state with a 3 ps lifetime immediately after excitation. This state precedes the formation of another excited state with a 32 ps lifetime. The decay of the latter state is followed by the appearance of a first product state that is assumed to represent lunii-R. In addition, 2,3-dihydrobiliverdin, which is considered to be an adequate model of the Pr chro-mophore, was included in the femtosecond studies. The absorption difference spectra recorded at various delay times show an immediate bleaching of the ground-state absorption. Simultaneously with bleaching a broad transient absorption appears between 410 and 525 nm. The data analysis yields similar kinetic components as they were observed in the decay of Pr. It is suggested from this finding that within the first tens of picoseconds after excitation the excited-state properties of Pr are mainly determined by the properties of the chromophore itself. 相似文献